Low-cost green hydrogen production possible with new breakthrough

Researchers at Hanyang University ERICA campus in South Korea have developed a new class of cobalt phosphide-based nanomaterials that significantly lower the cost of green hydrogen production. By adjusting boron doping and phosphorus content through metal-organic frameworks (MOFs), the team created catalysts with superior performance and affordability compared to conventional electrocatalysts. These materials exhibit large surface areas and mesoporous structures, enhancing their electrocatalytic activity for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The best-performing sample demonstrated notably low overpotentials of 248 mV for OER and 95 mV for HER, outperforming previously reported catalysts. The innovative synthesis involved growing cobalt-based MOFs on nickel foam, followed by boron doping via sodium borohydride treatment and phosphorization with sodium hypophosphite. Density functional theory (DFT) calculations confirmed that the combination of boron doping and optimized phosphorus content improved interactions with reaction intermediates, driving the enhanced